A zig-zag uranyl(v)-Mn(ii) single chain magnet with a high relaxation barrier.

نویسندگان

  • Lucile Chatelain
  • Floriana Tuna
  • Jacques Pécaut
  • Marinella Mazzanti
چکیده

The synthesis, structural characterization and magnetic properties of a 1D zig-zag coordination polymer based on a cation-cation [(U(V)O2)Mn(II)] repeated unit are reported; it shows single chain magnet (SCM) behaviour with a high energy barrier of 122 K.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A Uranium-Based UO2+–Mn2+ Single-Chain Magnet Assembled trough Cation–Cation Interactions**

Single-chain magnets (SCMs) are materials composed of magnetically isolated one-dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM behavior requires the fulfillment of stringent conditions for exchange and anisotropy interactions. Herein, we report the synthesis, the structure, and the magnetic characterization of the first actinide-containing SCM. The 5f-...

متن کامل

A single-chain magnet based on linear [Mn(III)2Mn(II)] units.

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [Mn(III)2Mn(II)] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn-carboxylate SCM with a linear architecture.

متن کامل

A tetranuclear cobalt(II) chain with slow magnetization relaxation.

A solvothermally derived tetranuclear cobalt(II) complex, [Co(4)(phen)(4)Cl(8)] (phen = phenanthroline), featuring a zig-zag backbone of {Co(μ(2)-Cl)(2)Co} planes, exhibits ferromagnetic exchange and slow relaxation of the magnetization and represents the first Co SMM with a linear core structure.

متن کامل

The difluoromethylene (CF2) group in aliphatic chains: Synthesis and conformational preference of palmitic acids and nonadecane containing CF2 groups

The syntheses of palmitic acids and a nonadecane are reported with CF2 groups located 1,3 or 1,4 to each other along the aliphatic chain. Specifically 8,8,10,10- and 8,8,11,11-tetrafluorohexadecanoic acids (6b and 6c) are prepared as well as the singly modified analogue 8,8-difluorohexadecanoic acid (6a). Also 8,8,11,11-tetrafluorononadecane (27) is prepared as a pure hydrocarbon containing a 1...

متن کامل

Defect complexes in carbon and boron nitride nanotubes.

The effect of defect complexes on the stability, structural and electronic properties of single-walled carbon nanotubes and boron nitride nanotubes is investigated using the ab initio pseudopotential density functional method implemented in the Castep code. We found more substantial atomic relaxations in the zig-zag carbon nanotube than the armchair one. We find that the B(C)B(c) defect introdu...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 51 56  شماره 

صفحات  -

تاریخ انتشار 2015